Absorption and Emission
Taking the electron transitions associated with visible and ultraviolet interactions with matter as an example, absorption of a photon will occur only when the quantum energy of the photon precisely matches the energy gap between the initial and final states. In the interaction of radiation with matter, if there is no pair of energy states such that the photon energy can elevate the system from the lower to the upper state, then the matter will be transparent to that radiation.
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